9/26/2007
| Season 1 | Disk 1 |
| 1 | Welcome to the Hellmouth |
| 2 | The Harvest |
| 3 | The Witch |
| 4 | Teacher's Pet |
| Season 1 | Disk 2 |
| 5 | Never Kill a Boy on the First Date |
| 6 | The Pack |
| 7 | Angel |
| 8 | I Robot, You Jane |
| Season 1 | Disk 3 |
| 9 | The Puppet Show |
| 10 | Nightmares |
| 11 | Out of Mind, Out of Sight |
| 12 | Prophecy Girl |
| Season 2 | Disk 1 |
| 13 | When She Was Bad |
| 14 | Some Assembly Required |
| 15 | School Hard |
| 16 | Inca Mummy Girl |
| Season 2 | Disk 2 |
| 17 | Reptile Boy |
| 18 | Halloween |
| 19 | Lie to Me |
| 20 | The Dark Age |
| Season 2 | Disk 3 |
| 21 | What's My Line? 1 |
| 22 | What's My Line? 2 |
| 23 | Ted |
| 24 | Bad Eggs |
| Season 2 | Disk 4 |
| 25 | Surprise |
| 26 | Innocence |
| 27 | Phases |
| 28 | Bewitched, Bothered And Bewildered |
| Season 2 | Disk 5 |
| 29 | Passion |
| 30 | Killed by Death |
| 31 | I Only Have Eyes For You |
| 32 | Go Fish |
| Season 2 | Disk 6 |
| 33 | Becoming, Part 1 |
| 34 | Becoming, Part 2 |
| Season 3 | Disk 1 |
| 35 | Anne |
| 36 | Dead Man's Party |
| 37 | Faith, Hope and Trick |
| 38 | Beauty and the Beasts |
| Season 3 | Disk 2 |
| 39 | Homecoming |
| 40 | Band Candy |
| 41 | Revelations |
| 42 | Lover's Walk |
| Season 3 | Disk 3 |
| 43 | The Wish |
| 44 | Amends |
| 45 | Gingerbread |
| Season 3 | Disk 4 |
| 46 | Helpless |
| 47 | The Zeppo |
| 48 | Bad Girls |
| 49 | Consequences |
| Season 3 | Disk 5 |
| 50 | Doppelgangland |
| 51 | Enemies |
| 52 | Earshot |
| 53 | Choices |
| Season 3 | Disk 6 |
| 54 | The Prom |
| 55 | Graduation Day (1) |
| 56 | Graduation Day (2) |
| Season 4 | Disk 1 |
| 57 | The Freshman |
| 58 | Living Conditions |
| 59 | The Harsh Light of Day |
| 60 | Fear, Itself |
| Season 4 | Disk 2 |
| 61 | Beer Bad |
| 62 | Wild At Heart |
| 63 | The Initiative |
| 64 | Pangs |
| Season 4 | Disk 3 |
| 65 | Something Blue |
| 66 | Hush |
| 67 | Doomed |
| Season 4 | Disk 4 |
| 68 | A New Man |
| 69 | The I In Team |
| 70 | Goodbye Iowa |
| 71 | This Year's Girl |
| Season 4 | Disk 5 |
| 72 | Who Are You? |
| 73 | Superstar |
| 74 | Where the Wild Things Are |
| 75 | New Moon Rising |
| Season 4 | Disk 6 |
| 76 | The Yoko Factor |
| 77 | Primeval |
| 78 | Restless |
| Season 5 | Disk 1 |
| 79 | Buffy vs. Dracula |
| 80 | Real Me |
| 81 | The Replacement |
| 82 | Out of My Mind |
| Season 5 | Disk 2 |
| 83 | No Place Like Home |
| 84 | Family |
| 85 | Fool For Love |
| 86 | Shadow |
| Season 5 | Disk 3 |
| 87 | Listening to Fear |
| 88 | Into the Woods |
| 89 | Triangle |
| Season 5 | Disk 4 |
| 90 | Checkpoint |
| 91 | Blood Ties |
| 92 | Crush |
| 93 | I Was Made to Love You |
| Season 5 | Disk 5 |
| 94 | The Body |
| 95 | Forever |
| 96 | Intervention |
| 97 | Tough Love |
| Season 5 | Disk 6 |
| 98 | Spiral |
| 99 | The Weight of the World |
| 100 | The Gift |
| Season 6 | Disk 1 |
| 101 | Bargaining (1) |
| 102 | Bargaining (2) |
| 103 | After Life |
| 104 | Flooded |
| Season 6 | Disk 2 |
| 105 | Life Serial |
| 106 | All The Way |
| 107 | Once More, With Feeling |
| 108 | Tabula Rasa |
| Season 6 | Disk 3 |
| 109 | Smashed |
| 110 | Wrecked |
| 111 | Gone |
| Season 6 | Disk 4 |
| 112 | Doublemeat Palace |
| 113 | Dead Things |
| 114 | Older and Far Away |
| 115 | As You Were |
| Season 6 | Disk 5 |
| 116 | Hell's Bells |
| 117 | Normal Again |
| 118 | Entropy |
| 119 | Seeing Red |
| Season 6 | Disk 6 |
| 120 | Villains |
| 121 | Two to Go |
| 122 | Grave |
| Season 7 | Disk 1 |
| 123 | Lessons |
| 124 | Beneath You |
| 125 | Same Time, Same Place |
| 126 | Help |
| Season 7 | Disk 2 |
| 127 | Selfless |
| 128 | Him |
| 129 | Conversations with Dead People |
| 130 | Sleeper |
| Season 7 | Disk 3 |
| 131 | Never Leave Me |
| 132 | Bring On The Night |
| 133 | Showtime |
| Season 7 | Disk 4 |
| 134 | Potential |
| 135 | The Killer In Me |
| 136 | First Date |
| 137 | Get It Done |
| Season 7 | Disk 5 |
| 138 | Storyteller |
| 139 | Lies My Parents Told Me |
| 140 | Dirty Girls |
| 141 | Empty Places |
| Season 7 | Disk 6 |
| 142 | Touched |
| 143 | End of Days |
| 144 | Chosen |